Well if you are going to be building water blocks for the chipset and gpu, i'd suggest the old fuel pump instead of a little pump from a shop bought kit.
Are the pump, radiator and resevoir going to be mounted inside the case or outside? Are you only going to cool the CPU, or maybe add chipset or GPU? What model case is it? (sizes, bays, etc) How many case fans are there? and how many spaces for fans are available inside the case? Do you use any of the lower drive bays at the front?
Copper pipes are great for this sort of thing. But you'll need to use some plastic hoses/connectors/corners if its all going to be kept inside the case.
Also, where are you? I can sugest plenty of parts and where to get them if you are in the UK :P
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